Тип публикации: статья из журнала
Год издания: 2009
Идентификатор DOI: 10.1007/s11172-009-0122-3
Ключевые слова: vinylidene complexes, heterometallic complexes, manganese, rhenium, palladium, platinum, IR and NMR spectroscopy, X-ray diffraction study
Аннотация: The reactions of Cp(CO)(2)Re=C=CHPh (2) with M(PPh(3))(4) (M = Pd, Pt) gave the mu-vinylidene complexes Cp(CO)(2)RePd(mu-C=CHPh)(PPh(3))(2) (3) and Cp(CO)(2)RePt(mu-C=CHPh)(PPh(3))(2) (1), respectively. The substitution of Ph(2)PCH(2)PPh(2) (dppm) for the PPh(3) ligands in 1 resulted in the formation of Cp(CO)RePt(mu-C(1)=C(2)HPh)(Показать полностьюmu-CO)(dppm) (4). The structure of complex 4 has been determined by single-crystal X-ray diffraction analysis. The structural and spectroscopic characteristics of complexes 1, 3, and 4 were compared with the corresponding parameters of the manganese-containing analogs Cp(CO)(2)MnPd(mu-C=CHPh)(PPh(3))(2) (5), Cp(CO)(2)MnPt(mu-C=CHPh)(PPh(3))(2) (6) and Cp(CO)(2)MnPt(mu-C=CHPh)(dppm) (7).
Журнал: RUSSIAN CHEMICAL BULLETIN
Выпуск журнала: Vol. 58, Is. 5
Номера страниц: 955-963
ISSN журнала: 10665285
Место издания: NEW YORK
Издатель: SPRINGER