Redox-mediated oxidation of cyclohexanone to adipic acid on oxide-nickel anode, with active forms of oxygen involved

Описание

Тип публикации: статья из журнала

Год издания: 2014

Идентификатор DOI: 10.1134/S1070427214040089

Аннотация: Redox-mediated oxidation of cyclohexanol to adipic acid on a porous anode with higher nickel oxides was studied, including the process involving active oxygen species (AOS) in situ generated from hydrogen peroxide and molecular oxygen in an alkaline electrolyte. It was found that the current efficiency by adipic acid grows upon addПоказать полностьюition of AOS. The selectivity of cyclohexanol oxidation to adipic acid depends on the current density, quantity of passed electricity, and method of AOS generation. It is demonstrated that use of AOS enables oxidation of cyclohexanol with a selectivity of adipic acid formation of up to 89% and its single-stage synthesis with a current efficiency of 50.2% at a current density of 22 mA cm(-2) and passing the theoretically required quantity of electricity.

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Издание

Журнал: RUSSIAN JOURNAL OF APPLIED CHEMISTRY

Выпуск журнала: Vol. 87, Is. 4

Номера страниц: 444-449

ISSN журнала: 10704272

Место издания: NEW YORK

Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER

Авторы

  • Chaenko N.V. (Siberian Federal University)
  • Kornienko G.V. (Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences)
  • Sokolenko V.A. (Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences)
  • Kornienko B.L. (Siberian Federal University)

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