A thermospectral setup for evaluating the content of unbound components in microscopic samples of an epoxy polymer

Описание

Тип публикации: статья из журнала

Год издания: 2012

Идентификатор DOI: 10.1134/S0020441212010198

Ключевые слова: Epoxy polymers, Extraction method, Optical measurement, Radiation absorption, Stoichiometric ratio, Epoxy resins, Hardening, Optical data processing, Function evaluation

Аннотация: A setup and a technique for optical measurements intended for evaluating the content of unbound compounds in an epoxy polymer are described. The principle of operation of the setup is based on measurements of the spectra of absorption of infrared (IR) radiation by condensed products of evaporation of unbound components. The needed Показать полностьюmass of a sample is about 0.01 g. The results of measurements of the IR radiation absorption as a function of the concentrations of the mixture components-ED-22 epoxy resin, isomethyltetrahydrophthalic anhydride (hardener), and a cure promoter (N integral D-606/2)-are presented. The relative content of chemically unbound components in the structure of a polymer matrix is evaluated as a function of the hardener concentration, thus allowing determination of the stoichiometric ratio of the initial components of an epoxy mixture. The obtained results are compared to those obtained by the extraction method.

Ссылки на полный текст

Издание

Журнал: INSTRUMENTS AND EXPERIMENTAL TECHNIQUES

Выпуск журнала: Vol. 55, Is. 2

Номера страниц: 294-297

ISSN журнала: 00204412

Место издания: NEW YORK

Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER

Авторы

  • Naumkin N.S. (Siberian Federal University)
  • Shestakov N.P. (Kirenskii Institute of Physics,Siberian Branch,Russian Academy of Sciences)
  • Ivanenko A.A. (Kirenskii Institute of Physics,Siberian Branch,Russian Academy of Sciences)
  • Shestakov A.B. (Siberian Federal University)
  • Kargin V.F. (Institute of Chemistry and Chemical Technology,Siberian Branch,Russian Academy of Sciences)

Вхождение в базы данных