Crystal structure and thermodynamic properties of germanate CuEu2Ge2O8

Описание

Тип публикации: статья из журнала

Год издания: 2022

Идентификатор DOI: 10.21883/PSS.2022.12.54406.460

Ключевые слова: copper-europium germanate, solid-phase synthesis, crystal structure, thermodynamic properties

Аннотация: Copper-europium germanate CuEu2Ge2O8 was obtained from the initial CuO, Eu2O3 and GeO2 oxides using solid-phase synthesis by annealing in air in the temperature range of 1223-1273 K. Its crystal structure was determined (space group Cm). The influence of temperature on high-temperature heat capacity of the synthesized germanate wasПоказать полностьюstudied by the differential scanning calorimetry method. It was found that the dependence of heat capacity on temperature has an extreme value related to a phase transition. The thermodynamic properties were calculated based on the experimental data about heat capacity.

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Издание

Журнал: Physics of the Solid State

Выпуск журнала: Vol. 64, Is. 12

Номера страниц: 2045-2048

ISSN журнала: 10637834

Персоны

  • Denisova L. T. (Siberian Federal University, Krasnoyarsk, Russia)
  • Molokeev M. S. (L.V. Kirensky Institute of Physics SB RAS, 660036 Krasnoyarsk, Russian Federation; Siberian Federal University, Krasnoyarsk, Russia)
  • Irtyugo L. A. (Siberian Federal University, Krasnoyarsk, Russia)
  • Belousova N. V. (Siberian Federal University, Krasnoyarsk, Russia)
  • Denisov V. M. (Siberian Federal University, Krasnoyarsk, Russia)

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