1. Главная
  2. Публикации
  3. Hydrogenation of Ethanol-Lignin of Larch Wood in Supercritical Ethanol in the Presence of Sulfated Catalysts ZrO2 and Pt/ZrO2 : научное издание

Hydrogenation of Ethanol-Lignin of Larch Wood in Supercritical Ethanol in the Presence of Sulfated Catalysts ZrO2 and Pt/ZrO2 : научное издание

Описание

Тип публикации: статья из журнала

Год издания: 2018

Идентификатор DOI: 10.17516/1998-2836-0102

Ключевые слова: larch ethanol-lignin, hydrogenation, supercritical ethanol, sulfated catalysts, ZrO2, 1 Pt/ZrO2, products, liquid, gaseous

Аннотация: The process of hydrogenation of larch ethanol-lignin in supercritical ethanol in the presence of sulfated catalysts - ZrO2 and 1% Pt/ZrO2 was investigated at 250 and 300 degrees C. The maximum conversion of ethanol-lignin (99,5 wt. %) and yield of liquid products (87,8 wt. %) were obtained in the presence of bifunctional catalyst PПоказать полностьюt/ZrO2 at temperature 300 degrees C. Catalysts ZrO2 and Pt/ZrO2 decrease of O/C and H/C atomic ratio in liquid products and increase by 2,2 2,4 times the yield of carbon oxides and methane increases as a results of intensification of deoxygenation reactions.

Ссылки на полный текст

Издание

Журнал: JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY

Выпуск журнала: Vol. 11, Is. 4

Номера страниц: 593-603

ISSN журнала: 19982836

Место издания: KRASNOYARSK

Издатель: SIBERIAN FEDERAL UNIV

Персоны

  • Sharypov Victor I. (FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, 50-24 Akademgorodok, Krasnoyarsk 660036, Russia; Siberian Fed Univ, 79 Svobodny, Krasnoyarsk 660041, Russia)
  • Beregovtsova Natalia G. (FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, 50-24 Akademgorodok, Krasnoyarsk 660036, Russia)
  • Baryshnikov Sergei V. (FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, 50-24 Akademgorodok, Krasnoyarsk 660036, Russia)
  • Miroshnikova Angelina V. (FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, 50-24 Akademgorodok, Krasnoyarsk 660036, Russia)
  • Taran Oxana P. (FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, 50-24 Akademgorodok, Krasnoyarsk 660036, Russia; Siberian Fed Univ, 79 Svobodny, Krasnoyarsk 660041, Russia)
  • Lavrenov Alexandr V. (Inst Hydrocarbons Proc SB RAS, 2,5th Kordnaya, Omsk 644040, RussiaArticle)
  • Kuznetsov Boris N. (FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, 50-24 Akademgorodok, Krasnoyarsk 660036, Russia; Siberian Fed Univ, 79 Svobodny, Krasnoyarsk 660041, Russia)

Вхождение в базы данных