Тип публикации: статья из журнала
Год издания: 2021
Идентификатор DOI: 10.17516/1998-2836-0263
Ключевые слова: levulinic acid, electrocatalytic hydrogenation, valeric acid, voltammetry, conversion, effectivity, process selectivity, preparative electrolysis, conversion effectivity
Аннотация: The electrochemical hydrogenation of levulinic acid in H2SO4 solution at aluminium, lead, graphite and glassy carbon electrodes is studied. The process is identified to proceed selectively to valeric acid. The conversion, selectivity and faradaic efficiency are significantly influenced by the material electrode nature. The levuliniПоказать полностьюc acid hydrogenation at glassy carbon is shown for the first time to proceed to valeric acid, and the process selectivity is affected by the concentration of surface functionalities. The electrochemical hydrogenation of levulinic acid in H2SO4 solution at aluminium, lead, graphite and glassy carbon electrodes is studied. The process is identified to proceed selectively to valeric acid. The conversion, selectivity and faradaic efficiency are significantly influenced by the material electrode nature. The levulinic acid hydrogenation at glassy carbon is shown for the first time to proceed to valeric acid, and the process selectivity is affected by the concentration of surface functionalities. © Siberian Federal University. All rights reserved
Журнал: JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY
Выпуск журнала: Vol. 14, Is. 4
Номера страниц: 561-569
Место издания: SIBERIAN FEDERAL UNIV
Издатель: 1