Тип публикации: статья из журнала
Год издания: 2014
Идентификатор DOI: 10.1134/S0036024414100069
Ключевые слова: nanopowders, platinum group metals, enlargement, differential scanning calorimetry, Iridium alloys, Platinum, Powder metals, Argon atmospheres, Chemisorbed oxygen, Exothermal effect, Mechanical mixtures, Nano powders, Platinum and palladiums
Аннотация: The behavior of palladium, rhodium, iridium, and platinum powders during their heating in an argon atmosphere was studied by differential scanning calorimetry (DSC). The DSC curves showed the exothermal peaks corresponding to the enlargement of the platinum group metal powders under study. Electron microscopy and XRD studies revealПоказать полностьюed that the particle size of highly disperse powders changed during the heating. Chemisorbed oxygen was removed from the powder surface above 800 K. During the heating of the mechanical mixture of highly disperse platinum and palladium powders, a solid solution formed with an exothermal effect.
Журнал: RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
Выпуск журнала: Vol. 88, Is. 10
Номера страниц: 1732-1738
ISSN журнала: 00360244
Место издания: NEW YORK
Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER