Тип публикации: статья из журнала
Год издания: 2016
Идентификатор DOI: 10.1016/j.jmmm.2016.02.062
Ключевые слова: Nickel zinc ferrite, Nanoparticles, Magnetic properties, MCD, Charge transfer, Dichroism, Ferrites, Magnetism, Nickel, Optical properties, Spectroscopy, Synthesis (chemical), Zinc, Zinc compounds, Annealing temperatures, External magnetic field, Intervalence charge transfer, Magnetic and magneto-optical properties, Magnetic circular dichroism spectra, Magnetic circular dichroisms, Magnetization dependence, Nickel Zinc ferrites, Nanomagnetics
Аннотация: Ni0.2Zn0.8Fe2O4 spinel nanoparticles have been synthesized by combustion method. Average particles size varies from 15.5 to 50.0 nm depending on annealing temperature. Correlations between particles size and magnetic and magneto-optical properties are investigated. Magnetization dependences on temperature and external magnetic fielПоказать полностьюd correspond to the sum of paramagnetic and superparamagnetic response. Critical size of single-domain transition is found to be 15.9 nm. Magnetic circular dichroism (MCD) studies of nickel zinc spinel are presented here for the first time. The features in magnetic circular dichroism spectrum are assigned to the one-ion d-d transitions in Fe3+ and Ni2+ ions, as well to the intersublattice and intervalence charge transfer transitions. The MCD spectrum rearrangement was revealed with the change of the nanoparticles size. (C) 2016 Elsevier B.V. All rights reserved.
Журнал: JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
Выпуск журнала: Vol. 408
Номера страниц: 206-212
ISSN журнала: 03048853
Место издания: AMSTERDAM
Издатель: ELSEVIER SCIENCE BV