Synthesis and Crystal Structure of Nitrosoruthenium Triammino Complex [RuNO(NH3)3Cl(H2O)]Cl2 : научное издание

Описание

Тип публикации: статья из журнала

Год издания: 2000

Аннотация: This paper reports on a procedure for the synthesis of the compound [RuNO(NH3)3Cl(H2O)]Cl2. The complex was studied by IR spectroscopy and X-ray phase and X-ray diffraction analyses. Crystal data for RuCl3N4O2H11: a = 13.151(2), b = 6.852(1), c = 10.361(1) A, V = 933.6(2) A2, space group mathPna2_1/math, Z = 4, dcalc = 2.181 g/cm3,Показать полностьюdexp = 2.178 g/cm3. The structure consists of the [RuNO(NH3)3Cl(H2O)]2+ complex cations and Cl- anions. The compound crystallizes as small orange red isometric orthorhombic crystals well soluble in water and insoluble in concentrated hydrochloric acid and organic solvents and is stable when stored in air.

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Издание

Журнал: Journal of Structural Chemistry

Выпуск журнала: Т. 41, 6

Номера страниц: 1030-1034

ISSN журнала: 00224766

Место издания: Новосибирск

Издатель: Pleiades Publishing, Ltd. (Плеадес Паблишинг, Лтд)

Персоны

  • Emel'yanov V.A. (Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences eva@che.nsk.su)
  • Baidina I.A. (Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences eva@che.nsk.su)
  • Gromilov S.A. (Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences eva@che.nsk.su)
  • Vasiliev A.D. (L. V. Kirenskii Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk)
  • Belyaev A.V. (Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences eva@che.nsk.su)

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