Тип публикации: статья из журнала
Год издания: 2013
Идентификатор DOI: 10.1016/j.micromeso.2012.11.010
Ключевые слова: Cenosphere, Hollow zeolite microsphere, NaA, NaX, Mullite, NaA
Аннотация: One-step procedure to fabricate hollow aluminosilicate microspheres with a composite NaA(NaX)/glass/mullite composite shell was demonstrated by the direct conversion of low-silica cenospheres (Si/Al = 1.8) separated from coal fly ash. The reported method does not involve seeding and structure-directing reagents. Composition of cenoПоказать полностьюspheres and the stirring of reactants at the optimal synthesis temperature (T=80 degrees C) and alkaline molarity (2.5 M NaOH) are parameters affected the formation of a monozeolitic phase (NaA or NaX). The influence of the silica-alumina composition of cenospheres on the type of zeolite phase formation is only revealed under stirring conditions. In the case of the low-silica cenospheres, NaA (LTA) zeolite crystallizes as a dominant phase (43 wt.%) (Si/Al = 1.8) under stirring of reactants, while the static conditions favor formation of the NaX (FAU) zeolite phase (45 wt.%). Crown Copyright (C) 2012 Published by Elsevier Inc. All rights reserved.
Журнал: MICROPOROUS AND MESOPOROUS MATERIALS
Выпуск журнала: Vol. 169
Номера страниц: 207-211
ISSN журнала: 13871811
Место издания: AMSTERDAM
Издатель: ELSEVIER SCIENCE BV