Тип публикации: статья из журнала

Год издания: 2025

Идентификатор DOI: 10.1002/ange.202515844

Аннотация: <jats:title>Abstract</jats:title><jats:p>Zero-dimension (0D) organic-inorganic hybrid metal halides are highly attractive as smart responsive luminescent materials, but the multiple-mode luminescence switch is rarely achieved and intrinsic solvochromism mechanism is unclear. Herein, we report a yellowish-green-emitting (Me<jats:subПоказать полностью>3</jats:sub>BzN)<jats:sub>3</jats:sub>Sb<jats:sub>2</jats:sub>Cl<jats:sub>9</jats:sub> (Me<jats:sub>3</jats:sub>BzN: trimethylbenzyl ammonium) single crystal, revealing quadruple/triple-mode luminescence switch with rapid response time (<1 s) and excellent recyclability (≥ 100 cycles) when triggered by moderately-polar and strongly-polar solvents. Significantly, the intrinsic solvochromism mechanism is systematically proposed, of which the reversibly multiple-mode luminescence tuning is closely related to solvent polarity, the moderate polarity can lead to luminescence redshift from 560 to 670 nm due to the increase of dipole moment for inorganic polyhedron. Besides, the small molecular solvent with strong polarity can insert into crystal and form “host-guest” system, inducing single crystal-single crystal phase transformation with structural disorder and Sb-Sb distance variation. Owing to the unique multiple-mode luminescence adjustment performance, (Me<jats:sub>3</jats:sub>BzN)<jats:sub>3</jats:sub>Sb<jats:sub>2</jats:sub>Cl<jats:sub>9</jats:sub> displays potential candidate in solvent detection, safety monitoring and information encryption scenarios. These findings highlight the significance of solvent polarity and molecule volume on the dynamic luminescence adjustment and offer guidance for the development of new smart responsive 0D hybrid antimony halides in advanced optical switchable fields.</jats:p>

Журнал: Angewandte Chemie

Выпуск журнала: Т. 137, № 41

Номера страниц: 202515844

ISSN журнала: 00448249

Издатель: John Wiley &amp; Sons, Incorporated

• Liao Hanrui (Faculty of Materials Science and Chemistry China University of Geosciences Wuhan 430074 P.R. China)
• Sun Jinxuan (Faculty of Materials Science and Chemistry China University of Geosciences Wuhan 430074 P.R. China)
• Li Wei (Faculty of Materials Science and Chemistry China University of Geosciences Wuhan 430074 P.R. China)
• Yang Hang (Faculty of Materials Science and Chemistry China University of Geosciences Wuhan 430074 P.R. China)
• Xie Linpeng (Faculty of Materials Science and Chemistry China University of Geosciences Wuhan 430074 P.R. China)
• Molokeev Maxim S. (Department of Physics Far Eastern State Transport University Khabarovsk 680021 Russia)
• Wei Yi (Faculty of Materials Science and Chemistry China University of Geosciences Wuhan 430074 P.R. China)
• Xia Fan (State key Laboratory of Biogeology and Environmental Geology China University of Geosciences 388 Lumo Road Wuhan 430074 P.R. China)
• Li Guogang (State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan 430200 P.R. China)

• РИНЦ (eLIBRARY.RU)