Тип публикации: статья из журнала

Год издания: 2013

Идентификатор DOI: 10.1134/S0022476613020157

Ключевые слова: crystal structure, enrofloxacinium cation, tetrabromidodichloridostannate(IV) anion, hydrogen bonds

Аннотация: A new compound EnrH(3)[SnBr3.46Cl2.54]center dot H2O, where EnrH (3) (2+) is the enrofloxacinium cation (C19H24FN3O (3) (2+) ), is synthesized and its crystal and molecular structure is determined. Crystallographic data for enrofloxacinium tetrabromidodichloridostannate(IV) monohydrate are as follows: a = 17.1262(19) , b = 10.3435(Показать полностью11) , c = 17.2582(19) , beta = 119.203(1)A degrees, V = 2640.5(4) (3), space group P2(1)/c, Z = 4. Hydrogen bonds form a branched three-dimensional network linking EnrH (3) (2+) , [SnBr3.46Cl2.54](2-), and water molecules. The structure is also stabilized by the pi-pi interaction of EnrH (3) (2+) aromatic rings.

Журнал: JOURNAL OF STRUCTURAL CHEMISTRY

Выпуск журнала: Vol. 54, Is. 2

Номера страниц: 377-382

ISSN журнала: 00224766

Место издания: NEW YORK

Издатель: SPRINGER

• Golovnev N.N. (Siberian Federal University)
• Golovneva I.I. (Siberian Federal University)
• Molokeev M.S. (L. V. Kirensky Institute of Physics,Siberian Division,Russian Academy of Sciences)
• Glushchenko G.A. (L. V. Kirensky Institute of Physics,Siberian Division,Russian Academy of Sciences)

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