Synthesis and study of structural, thermodynamic, and magnetic properties of Na (x) Li1-x FeGe2O6 (x=0.1-0.9) compounds

Описание

Тип публикации: статья из журнала

Год издания: 2016

Идентификатор DOI: 10.1134/S1063783416070143

Аннотация: The properties of Na (x) Li1-x FeGe2O6 (x = 0.1-0.9) solid solutions obtained via a solid-phase synthesis have been measured by X-ray diffraction, calorimetry, and magnetic method. The order-disorder transformations in low-dimensional Na (x) Li1-x FeGe2O6 (x = 0.1-0.9) spin systems with predominately antiferromagnetic exchange inteПоказать полностьюraction have been revealed in the low-temperature susceptibility dependences. The study of thermal and physical properties has confirmed that substituting the sodium ions with the lithium ones induces the first-order structural phase transitions of the displacement type which are characterized by a symmetry change in monoclinic crystals from high-temperature C2/c space group to low-temperature P2(1)/c space group.

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Издание

Журнал: PHYSICS OF THE SOLID STATE

Выпуск журнала: Vol. 58, Is. 7

Номера страниц: 1361-1370

ISSN журнала: 10637834

Место издания: NEW YORK

Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER

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