Exploring temperature-dependent photoluminescence dynamics of colloidal CdSe nanoplatelets using machine learning approach

Описание

Тип публикации: статья из журнала

Год издания: 2024

Идентификатор DOI: 10.1038/s41598-024-81200-9

Аннотация: The study explore machine learning (ML) techniques to predict temperature-dependent photoluminescence (PL) spectra in colloidal CdSe nanoplatelets (NPLs), leveraging polynomial regression models trained on experimental data from 85 to 270 K spanning temperatures to forecast PL spectra backward to 0 K and forward to 300 K. 6th-degreПоказать полностьюe polynomial models with Tweedie regression were optimal for band energy ( $$B_1$$ ) predictions up to 300 K, while 9th-degree models with LassoLars and Linear Regression regressors were suitable for backward predictions to 0 K. For exciton energy ( $$B_2$$ ), the Lasso model of degree 5 and the Ridge model of degree 4 performed well up to 300 K, while the Tweedie model of degree 2 and Theil-Sen model of degree 2 showed promise for predictions to 0 K. Furthermore, a GA-based approach was utilized to fit experimental data to theoretical model of Fan and Varshni equations, facilitating a comparative analysis with the ML-predicted curves.

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Издание

Журнал: Scientific Reports

Выпуск журнала: Т. 14, 1

Номера страниц: 30878

ISSN журнала: 20452322

Место издания: Berlin

Издатель: Springer Nature

Персоны

  • Malashin Ivan P. (Bauman Moscow State Technical University, Moscow, Russia, 105005)
  • Daibagya Daniil (Bauman Moscow State Technical University, Moscow, Russia, 105005)
  • Tynchenko Vadim (Bauman Moscow State Technical University, Moscow, Russia, 105005)
  • Nelyub Vladimir (Bauman Moscow State Technical University, Moscow, Russia, 105005)
  • Borodulin Aleksei (Bauman Moscow State Technical University, Moscow, Russia, 105005)
  • Gantimurov Andrei (Bauman Moscow State Technical University, Moscow, Russia, 105005)
  • Selyukov Alexandr (P.N. Lebedev Physical Institute of The Russian Academy of Sciences, Moscow, Russia, 119991)
  • Ambrozevich Sergey (P.N. Lebedev Physical Institute of The Russian Academy of Sciences, Moscow, Russia, 119991)
  • Vasiliev Roman (Lomonosov Moscow State University, Moscow, Russia, 119991)

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