Controlled synthesis of fullerenes and endohedral metallofullerenes in high frequency arc discharge

Описание

Тип публикации: статья из журнала

Год издания: 2016

Идентификатор DOI: 10.1080/1536383X.2016.1207062

Ключевые слова: Fullerene, Endohedral metallofullerenes, High frequency arc discharge, Pressure, Mass spectrum, Helium, Mass spectrometry, Metals, Arc discharge, Controlled synthesis, Formation mechanism, Helium atmosphere, High frequency HF, Higher fullerenes, Mass spectra, Fullerenes

Аннотация: The article presents the high-frequency arc discharge setup operating in helium atmosphere and applicable for the syntheses of carbon condensate with different dispersion and structure, along with fullerenes and endohedral metallofullerenes. It also highlights how the change of helium pressure in chamber can control the amount and Показать полностьюcomposition of products in carbon condensate. The setup can be applied for the purposes of analysis, for instance in order to obtain information about the process of fullerenes and endohedral metallofullerenes formation. Also, the fact that the yield of higher fullerenes is increasing with the pressure rise, whereas the yield of endohedral metallofullerenes is decreasing suggests different formation mechanisms.

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Издание

Журнал: FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES

Выпуск журнала: Vol. 24, Is. 11

Номера страниц: 675-678

ISSN журнала: 1536383X

Место издания: PHILADELPHIA

Издатель: TAYLOR & FRANCIS INC

Персоны

  • Churilov G. (Kirensky Institute of Physics SB RAS)
  • Vnukova N. (Siberian Federal University)
  • Dudnik A. (Leibniz Institute for Solid State and Materials Research)
  • Glushenko G. (Kirensky Institute of Physics SB RAS)
  • Popov A. (Leibniz Institute for Solid State and Materials Research)
  • Samoylova N. (Leibniz Institute for Solid State and Materials Research)