Тип публикации: статья из журнала
Год издания: 2012
Идентификатор DOI: 10.1016/j.jmmm.2011.07.044
Ключевые слова: Transition metal oxyborate, Distinct crystallographic position, Spin glass magnetic ordering, Antiferro-magnetic interactions, Crystallographic position, Isostructural, K points, Magnetic properties of co, Mn ions, Needle shape, Temperature dependencies, X-ray diffraction data, Antiferromagnetism, Cobalt, Cobalt compounds, Glass, Magnetic properties, Manganese, Paramagnetism, Single crystals, Spin glass, X ray diffraction, Crystal structure
Аннотация: The needle shape single crystals Co3-x MnxO2BO3 with ludwigite structure have been prepared. According to the X-ray diffraction data the preferable character of distinct crystallographic positions occupation by Mn ions is established. Magnetization field and temperature dependencies are measured. Paramagnetic Curie temperature valuПоказать полностьюe Theta = -100 K points out the predominance of antiferromagnetic interactions. Spin-glass magnetic ordering takes the onset at T-N=41 K. The crystallographic and magnetic properties of Co3O2BO3:Mn are compared with the same for the isostructural analogs Co3O2BO3 and CoO2BO3:Fe. (C) 2011 Elsevier B.V. All rights reserved.
Журнал: JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
Выпуск журнала: Vol. 324, Is. 6
Номера страниц: 923-927
ISSN журнала: 03048853
Место издания: AMSTERDAM
Издатель: ELSEVIER SCIENCE BV