Тип публикации: статья из журнала
Год издания: 2015
Идентификатор DOI: 10.1007/s10973-014-4196-2
Ключевые слова: Thermal analysis, Oxidation, Kinetics, Titanium diboride powders, Activation energy, Enzyme kinetics, Powders, Thermoanalysis, Activation energy E, Fractional order, Iso-conversional method, Most likely, Oxidation reactions, Oxygen diffusion, Temperature range
Аннотация: The kinetic parameters of TiB2 powders oxidation of different dispersions were estimated by Coats-Redfern and Ozawa-Flynn-Wall methods. Based on the isoconversional method, it was found that the investigated reaction is most likely of the fractional order and the activation energy E-A dependence during the oxidation reaction is of Показать полностьюthe complicated behavior. Using the Coats-Redfern method the E-A values were estimated for four temperature ranges: E-A congruent to 300-400 kJ/mol (
Журнал: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Выпуск журнала: Vol. 119, Is. 1
Номера страниц: 123-130
ISSN журнала: 13886150
Место издания: DORDRECHT
Издатель: SPRINGER