Improving of thermoelectric figure of merit in Sr0.925Dy0.075TiO3 ceramics : научное издание

Описание

Тип публикации: статья из журнала

Год издания: 2024

Идентификатор DOI: 10.1016/j.ceramint.2024.10.351

Аннотация: Rare earth doped SrTiO3 is one of the most promising oxide materials meeting the safety and stability requirements for potential applications in thermoelectric converters. This work aims to assess the feasibility of engineering SrTiO3-based materials to improve their thermoelectric performance. A comparative analysis of the thermoeПоказать полностьюlectric properties of Sr0.925Dy0.075TiO3 ceramic samples obtained from preliminarily mechanically activated Sr0.925Dy0.075TiO3 nano-powder by two methods – solid-state reaction synthesis and spark plasma sintering – was carried out. Significant differences in the morphology of the samples lead to significant differences in the temperature dependences of electrical resistivity and the Seebeck coefficient. Ceramics obtained by solid-state reaction synthesis exhibit lower porosity and lower electrical resistivity. The thermoelectric power factor of such ceramics is 2–3 times higher than that of samples obtained by spark plasma sintering. The obtained value of thermoelectric figure of merit ZT = 0.41 at T = 673 K for Sr0.925Dy0.075TiO3 is the highest value among n-type oxide thermoelectric ceramics at a given temperature and maintains a tendency to increase with increasing temperature.

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Издание

Журнал: Ceramics International

Выпуск журнала: Т. 50, 24 Part C

Номера страниц: 55026-55033

ISSN журнала: 02728842

Издатель: Elsevier Science Publishing Company, Inc.

Персоны

  • Dudnikov V.A. (Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences)
  • Orlov Yu.S. (Siberian Federal University)
  • Vereshchagin S.N. (Institute of Chemistry and Chemical Technology, Federal Research Center KSC SB RAS, Russian Academy of Sciences)
  • Belov A.A. (Institute of High Technology and Advanced Materials, Far Eastern Federal University)
  • Solovyov L.A. (Institute of Chemistry and Chemical Technology, Federal Research Center KSC SB RAS, Russian Academy of Sciences)
  • Borus A.A. (Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences)
  • Zharkov S.M. (Siberian Federal University)
  • Zeer G.M. (Siberian Federal University)
  • Ustyuzhanin Yu.N. (Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences)
  • Volochaev M.N. (Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences)
  • Bondarev V.S. (Siberian Federal University)
  • Ovchinnikov S.G. (Siberian Federal University)

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