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Chemistry of vinylidene complexes. XXIII. Binuclear rhenium-palladium vinylidene bridged complexes, their reactions with diiron nonacarbonyl

Описание

Тип публикации: статья из журнала

Год издания: 2014

Идентификатор DOI: 10.1016/j.jorganchem.2014.07.024

Ключевые слова: Rhenium, Palladium, Iron, Vinylidene complexes, Heterometallic complexes, Cyclic voltammetry, Nuclear magnetic resonance spectroscopy, Palladium compounds, Synthesis (chemical), X ray diffraction, Diphosphines, Single crystal x-ray diffraction, Trinuclear, Rhenium compounds

Аннотация: The reaction of [Cp(CO)(2)Re-C-CHPh] (1) with [Pd(PPh3)(4)] followed by the treatment of resulting [Cp(CO)(2)RePd(mu-C=CHPh)(PPh3)(2)] (2) with diphosphines (dppe, dppp) gave new complexes [Cp(CO)(2)RePd(mu-C=CHPh)(dppe)] (3) and [Cp(CO)(2)RePd(mu-C=CHPh)(dppp)] (4). Treatment of the synthesized complexes with [Fe-2(CO)(9)] led to Показать полностьюmixtures of [Cp(CO)(2)ReFe(mu-C=CHPh)(CO)(4)] (5), [(dppe) PdFe2(CO)(8)] (6), [CpReFe2(mu(3)-C=CHPh)(CO)(8)] (7), [CpReFePd(mu(3)-C=CHPh)(CO)(5)(dppe)] (8) and of 5, [(dppp)PdFe2(CO)(8)] (9), [CpReFePd(mu(3)-C=CHPh)(CO)(5)(dppp)] (10), respectively. The main products of both reactions were trinuclear mu(3)-vinylidene clusters 8 and 10. Reactions of the trinuclear mu(3)-vinylidene ReFePd clusters 8 and 10 with Fe-2(CO)(9) were also studied. New complexes were characterized by IR, H-1, C-13, P-31 NMR spectroscopy and cyclic voltammetry. The structure of [CpReFe2(mu(3)-C=CHPh)(CO)(8)] was determined by single-crystal X-ray diffraction. (C) 2014 Elsevier B. V. All rights reserved.

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Издание

Журнал: JOURNAL OF ORGANOMETALLIC CHEMISTRY

Выпуск журнала: Vol. 770

Номера страниц: 42-50

ISSN журнала: 0022328X

Место издания: LAUSANNE

Издатель: ELSEVIER SCIENCE SA

Персоны

  • Verpekin V.V. (Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences)
  • Kondrasenko A.A. (Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences)
  • Chudin O.S. (Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences)
  • Burmakina G.V. (Siberian Federal University)
  • Pavlenko N.I. (Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences)
  • Rubaylo A.I. (Siberian Federal University)
  • Vasiliev A.D. (Krasnoyarsk Scientific Center, Siberian Branch of the RAS)

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