Тип публикации: статья из журнала

Год издания: 2015

Идентификатор DOI: 10.1134/S0022476615040253

Ключевые слова: rhenium, iron, platinum, vinylidene complexes, heterometallic complexes, clusters, single crystal X-ray diffraction study

Аннотация: The X-ray diffraction study of a new heterometallic cluster CpReFePt(mu 3-C=CHPh)(CO)(5)[P(OPr (i) )(3)](2) is performed. The crystallographic characteristics are as follows: a = 11.0275(4) , b = 33.0367(12) , c = 12.2691(5) , beta = 98.3660(10)A degrees, V = 4422.2(3) (3), space group P2(1)/n, Z = 4, d (calc) = 1.744 g/cm(3). The Показать полностьюcluster contains the phenylvinylidene ligand coordinated with a trimetallic core in the form of a Re-Fe-Pt chain (the Re-Fe and Fe-Pt bond lengths are 2.794(7) and 2.628(1) respectively; the Re center dot center dot center dot Pt distance is 3.354(1) ).

Журнал: JOURNAL OF STRUCTURAL CHEMISTRY

Выпуск журнала: Vol. 56, Is. 4

Номера страниц: 774-776

ISSN журнала: 00224766

Место издания: NEW YORK

Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER

• Verpekin V.V. (Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk, Russia)
• Chudin O.S. (Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk, Russia)
• Piryazev D.A. (Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia; Novosibirsk Natl Res State Univ, Novosibirsk, Russia)
• Rubaylo A.I. (Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk, Russia; Russian Acad Sci, Krasnoyarsk Sci Ctr, Siberian Branch, Krasnoyarsk, Russia; Siberian Fed Univ, Krasnoyarsk, Russia)
• Gromilov S.A. (Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia; Novosibirsk Natl Res State Univ, Novosibirsk, Russia)
• Semeikin O.V. (Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow, Russia)

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