Lattice Doping of Lanthanide Ions in Cs 2 AgInCl 6 Nanocrystals Enabling Tunable Photoluminescence : научное издание

Описание

Тип публикации: статья из журнала

Год издания: 2021

Идентификатор DOI: 10.34133/2021/2585274

Аннотация: <jats:p> Lead-free halide double perovskite Cs <jats:sub>2</jats:sub> AgInCl <jats:sub>6</jats:sub> has become the research hotspot in the optoelectronic fields. It is a challenge to utilize the lattice doping by different lanthanide ions with rich and unique photoluminescence (PL) emissions for emerging photonic applications. HereПоказать полностью, we successfully incorporated Dy <jats:sup>3+</jats:sup>, Sm <jats:sup>3+</jats:sup>, and Tb <jats:sup>3+</jats:sup> ions into Cs <jats:sub>2</jats:sub> AgInCl <jats:sub>6</jats:sub> nanocrystals (NCs) by the hot-injection method, bringing diverse PL emissions of yellowish, orange, and green light in Cs <jats:sub>2</jats:sub> AgInCl <jats:sub>6</jats:sub> :Ln <jats:sup>3+</jats:sup> (Ln <jats:sup>3+</jats:sup>  = Dy <jats:sup>3+</jats:sup>, Sm <jats:sup>3+</jats:sup>, Tb <jats:sup>3+</jats:sup> ). Moreover, benefiting from the energy transfer process, Sm <jats:sup>3+</jats:sup> and Tb <jats:sup>3+</jats:sup> ion-codoped Cs <jats:sub>2</jats:sub> AgInCl <jats:sub>6</jats:sub> NCs achieved tunable emission from green to yellow orange and a fluorescent pattern from the as-prepared NC-hexane inks by spray coating was made to show its potential application in fluorescent signs and anticounterfeiting technology. This work indicates that lanthanide ions could endow Cs <jats:sub>2</jats:sub> AgInCl <jats:sub>6</jats:sub> NCs the unique and tunable PL properties and stimulate the development of lead-free halide perovskite materials for new optoelectronic applications. </jats:p>

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Издание

Журнал: Energy Material Advances

Выпуск журнала: Т. 2021

ISSN журнала: 20971133

Издатель: American Association for the Advancement of Science (AAAS)

Персоны

  • Liu Ying (The Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Science and Engineering, University of Science and Technology, Beijing, China)
  • Molokeev Maxim S. (Department of Physics, Far Eastern State Transport University, Russia)
  • Xia Zhiguo (The State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, School of Materials Science and Engineering, South China University of Technology, China)

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