Тип публикации: статья из журнала
Год издания: 2012
Идентификатор DOI: 10.1134/S0036023612040250
Ключевые слова: Amino group, Bismuth complexes, N-methylthiourea, Oxygen atom, Sulfur atoms, Bismuth, Hydrogen bonds, Oxygen, Sulfur, Atoms
Аннотация: A bismuth(III) complex of N-methylthiourea (Mtu, C2H6N2S) [Bi(C2H6N2S)(6)](ClO4)(3) has been synthesized, and its crystal structure has been determined. The structure is built of octahedral Bi(Mtu) (6) (3+) cations and ClO (4) (-) anions. Sulfur atoms are coordinated to bismuth(III) (at axis 2) at octahedron vertices (Bi-S, 2.7670(Показать полностью8), 2.8142(8), and 2.8315(8) ); angles SBiS vary from 82.26(3)A degrees to 96.13(2)A degrees. The presence of amino groups and oxygen atoms in the structure results in the emergence of numerous hydrogen bonds (HBs). All H atoms of amino groups are involved in HBs; one of them is bound to the sulfur atom. One of the oxygen atoms of ClO (4) (-) anions does not participate in HBs.
Журнал: RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Выпуск журнала: Vol. 57, Is. 4
Номера страниц: 525-527
ISSN журнала: 00360236
Место издания: NEW YORK
Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER