Тип публикации: статья из журнала
Год издания: 2024
Идентификатор DOI: 10.1002/chem.202402084
Аннотация: <jats:title>Abstract</jats:title><jats:p>Complex oxides Eu<jats:sub>2</jats:sub>MeO<jats:sub>6</jats:sub> (Me–Mo, W), Eu<jats:sub>2</jats:sub>W<jats:sub>2</jats:sub>O<jats:sub>9</jats:sub> were obtained by a solid-phase reaction between binary oxides. The thermodynamic and kinetic mechanisms of the reaction processes were establishПоказать полностьюed using a variety of physical-chemical methods. All compounds obtained in this work crystallize in the low-symmetry monoclinic system, forming complex framework structures, which determine a set of very valuable physical-chemical properties. Comparison of experimental Kubelka-Munk functions and DFT- calculated absorption spectra shows adequate agreement and reveals the origin of the fundamental absorption. In addition, the deficiency in DFT calculations in the part of mutual contribution of CTBs of Mo−O and W−O, from one side, and Eu−O contributions, from the other side, is reported. Calculations of absorption spectra are shown to be superior to band structure analysis in the determination of optical band gaps. Additionally, luminescent properties of Eu<jats:sub>2</jats:sub>MeO<jats:sub>6</jats:sub> and Eu<jats:sub>2</jats:sub>W<jats:sub>2</jats:sub>O<jats:sub>9</jats:sub> compounds were investigated. These studies provide a better understanding of the electronic and optical properties of the compounds Eu<jats:sub>2</jats:sub>MeO<jats:sub>6</jats:sub> and Eu<jats:sub>2</jats:sub>W<jats:sub>2</jats:sub>O<jats:sub>9</jats:sub>, along with their potential applications in various areas.</jats:p>
Журнал: Chemistry
Выпуск журнала: Т. 30, № 53
Номера страниц: 202402084
ISSN журнала: 09476539
Издатель: Wiley Interscience