Synthesis and Optical Properties of Nickel-Doped Copper Metaborate Crystals : научное издание

Описание

Тип публикации: статья из журнала

Год издания: 2023

Идентификатор DOI: 10.1134/s0030400x23060127

Ключевые слова: 3d-ions, crystal growth, optical spectroscopy, magnetic ordering, cuprates, optics, lasers, photonics, optical devices

Аннотация: This work presents information on the growth and spectroscopic study of single crystals of copper metaborate doped with nickel Cu1–<i>x</i>Ni<i>x</i>B2O4 (<i>x</i> <i>=</i> 0.05, 0.1). In the absorption spectra of both crystals, satellites related to Cu centers distorted by impurity Ni atoms were observed near the lines of zero phonon transitions. Polarization studies in the isotropic <i>ab</i>-plane of the tetragonal crystal Cu1–<i>x</i>Ni<i>x</i>B2O4 show the presence of linear magnetic dichroism in the magnetically ordered state, which was previously observed both in manganese-doped and undoped copper metaborates CuB2O4. The temperature of magnetic phase transitions into the collinear antiferromagnetic and into helicoidal structures, <i>T</i><i>N</i> <i>=</i> 19.1 K and <i>T</i> * <i>=</i> 8.6 K, respectively, were determined from the temperature dependence of the dichroic signal.

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Издание

Журнал: Optics and Spectroscopy

Выпуск журнала: Т.131, 8

Номера страниц: 717-722

ISSN журнала: 0030400X

Место издания: Москва

Издатель: Pleiades Publishing, Ltd. (Плеадес Паблишинг, Лтд)

Персоны

  • Molchanova A. D. (Institute of Spectroscopy, Russian Academy of Sciences)
  • Moshkina E. M. (Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences)
  • Molokeev M. S. (Scientific and Innovation Department, Kemerovo State University)
  • Tropina E. V. (Institute of Spectroscopy, Russian Academy of Sciences)
  • Bovina A. F. (Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences)
  • Boldyrev K. N. (Institute of Spectroscopy, Russian Academy of Sciences)

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