Тип публикации: статья из журнала
Год издания: 2018
Идентификатор DOI: 10.1016/j.moistruc.2018.03.020
Ключевые слова: Rhenium, Platinum, Vinylidene complexes, Heterometallic complexes, Electrochemistry
Аннотация: The novel heterobinuclear mu-vinylidene complex [Cp(CO)(2)Re(mu-C=CHPh)Pt(PPh3)(CO)%(1) was isolated from the reaction mixture of [Cp(CO)(2)Re(R-C=CHPh)Fe(CO)(4)%and Pt(PPh3)(4) for the first time. Alternative high-yield synthetic approaches to 1 were developed including the reactions of [Cp(CO)(2)Re(mu-C=CHPh) Pt(PPh3)(2)%(2) withПоказать полностьюCo-2(CO)(8) and Rh(acac)(CO)(2). The complex was characterized by IR and H-1, C-13 and P-31 NMR spectroscopy, a molecular structure of 1 was determined by X-ray diffraction analysis. The electrochemical behavior of the new complex was studied by cyclic voltammetry at platinum or glassed carbon electrodes and by dc polarography at a dropping mercury electrode. (C) 2018 Elsevier B.V. All rights reserved.
Журнал: JOURNAL OF MOLECULAR STRUCTURE
Выпуск журнала: Vol. 1163
Номера страниц: 308-315
ISSN журнала: 00222860
Место издания: AMSTERDAM
Издатель: ELSEVIER SCIENCE BV