Investigation of the effect of oxygen partial pressure on the phase composition of copper oxide nanoparticles by vacuum arc synthesis : научное издание

Описание

Тип публикации: статья из журнала

Год издания: 2022

Идентификатор DOI: 10.21883/tp.2022.15.55268.157-21

Аннотация: <jats:p> Copper oxide nanoparticles were obtained in the plasma of a low-pressure arc discharge. The effect of the partial pressure of oxygen (10-40%) on the physical properties of the deposited nanoparticles has been studied. X-ray diffraction analysis shows that the cubic structure of Cu<jats:sub>2</jats:sub>O changes to monoclinПоказать полностьюic CuO with increasing O<jats:sub>2</jats:sub> pressure. The results of Raman spectroscopy further confirmed the phase variations of copper-based oxide nanoparticles. X-ray photoelectron spectroscopy confirmed the change in the binding energy in the oxidation state of nanoparticles. The optical band gap of the deposited Cu<jats:sub>2</jats:sub>O is 2.12 eV, while that of CuO is 1.79-1.82 eV. Keywords: vacuum arc, oxides, nanoparticles, plasma-chemical reactions. </jats:p>

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Издание

Журнал: Technical Physics

Выпуск журнала: Т. 67, 15

Номера страниц: 2410

ISSN журнала: 10637842

Издатель: Ioffe Institute Russian Academy of Sciences

Персоны

  • Ushakov A. V. (Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Russia)
  • Karpov I. V. (Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Russia)
  • Fedorov L. Yu. (Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Russia)
  • Goncharova E. A. (Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Russia)
  • Brungardt M. V. (Siberian Federal University, Krasnoyarsk, Russia)
  • Дёмин В. Г. (Siberian Federal University, Krasnoyarsk, Russia)

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