Fractionation of Aspen Wood to Produce Microcrystalline, Microfibrillated and Nanofibrillated Celluloses, Xylan and Ethanollignin : научное издание

Описание

Тип публикации: статья из журнала

Год издания: 2023

Идентификатор DOI: 10.3390/polym15122671

Ключевые слова: aspen wood, fractionation, xylan, ethanollignin, microcrystalline, microfibrillated and nanofibrillated celluloses

Аннотация: A new method for extractive-catalytic fractionation of aspen wood to produce microcrystalline (MCC), microfibrillated (MFC), nanofibrilllated (NFC) celluloses, xylan, and ethanollignin is suggested in order to utilize all of the main components of wood biomass. Xylan is obtained with a yield of 10.2 wt.% via aqueous alkali extractiПоказать полностьюon at room temperature. Ethanollignin was obtained with a yield of 11.2 wt.% via extraction with 60% ethanol from the xylan-free wood at 190 °C. The lignocellulose residue formed after the extraction of xylan and ethanollignin was subjected to catalytic peroxide delignification in the acetic acid-water medium at 100 °C in order to obtain microcrystalline cellulose. MCC is hydrolyzed with 56% sulfuric acid and treated with ultrasound to produce microfibrillated cellulose and nanofibrillated cellulose. The yields of MFC and NFC were 14.4 and 19.0 wt.%, respectively. The average hydrodynamic diameter of NFC particles was 36.6 nm, the crystallinity index was 0.86, and the average zeta-potential was 41.5 mV. The composition and structure of xylan, ethanollignin, cellulose product, MCC, MFC, and NFC obtained from aspen wood were characterized using elemental and chemical analysis, Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) analyses, Gas chromatography (GC), Gel permeation-chromatography (GPC), Scanning electron microscopy (SEM), Atomic force microscopy (AFM), Dynamic light scattering (DLS), Thermal gravimetric analysis (TGA).

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Издание

Журнал: Polymers

Выпуск журнала: Т.15, 12

Номера страниц: 2671

ISSN журнала: 20734360

Место издания: Basel

Издатель: MDPI

Персоны

  • Kuznetsov Boris N. (Department of Non-Ferrous Metals and Materials Science, Siberian Federal University)
  • Chudina Anna I. (Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences)
  • Kazachenko Aleksandr S. (Department of Non-Ferrous Metals and Materials Science, Siberian Federal University)
  • Fetisova Olga Yu. (Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences)
  • Borovkova Valentina S. (Department of Non-Ferrous Metals and Materials Science, Siberian Federal University)
  • Vorobyev Sergei A. (Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences)
  • Karacharov Anton A. (Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences)
  • Gnidan Elena V. (Department of Non-Ferrous Metals and Materials Science, Siberian Federal University)
  • Mazurova Elena V. (Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences)
  • Skripnikov Andrey M. (Department of Non-Ferrous Metals and Materials Science, Siberian Federal University)
  • Taran Oxana P. (Department of Non-Ferrous Metals and Materials Science, Siberian Federal University)

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