Crystallization and Decomposition of Compounds with the Aurivillius Crystal Structure in the Bi2GeO5–Bi2SiO5 Pseudobinary Metastable System : научное издание


Тип публикации: статья из журнала

Год издания: 2023

Идентификатор DOI: 10.1134/S0031918X23700102

Ключевые слова: Bi2GeO5-Bi2SiO5, metastable state, crystallization, decomposition, partial substitution

Аннотация: The possibility of partial substitution of Si for Ge in the structure of Bi2GeO5 during synthesis from the melt and the effect of the substitution on the structure of the synthesized material have been studied. The microstructure of the synthesized compounds after their complete decomposition has been investigated. Using the phase Показать полностьюpowder X-ray diffraction- and optical microscopy methods, it has been found that metastable phases of bismuth silicate and germanate with structures of the Aurivillius type form a continuous series of solid solutions. It is shown that a mixed structure composed of large Bi4Si(Ge)3O12 crystals and the Bi12Si(Ge)O20 + Bi4Si(Ge)3O12 point eutectic is obtained after the decomposition of compounds of the Bi2SiO5–Bi2GeO5 quasi-binary system, regardless of the percentage of substitution of Si for Ge. Upon slow heating up to annealing temperatures (at a rate of 13.5°C/min), a structure of decomposition that is more finely dispersed and uniform than the structure obtained upon rapid heating (when charg the material into an already preheated furnace), which is more coarsely grained and inhomogeneous. Moreover, regions with a large structure similar to a dendritic one can appear in the material when the contents of silicon and germanium oxides in the alloy are close to each other (20/30–30/20 mol %). Such regions differ slightly in chemical composition from the surrounding material and appear during both slow and rapid heating of the material to annealing temperatures.

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Журнал: The Physics of Metals and Metallography

Выпуск журнала: Т.124, 2

Номера страниц: 205-216

ISSN журнала: 0031918X

Место издания: Екатеринбург

Издатель: Pleiades Publishing, Ltd. (Плеадес Паблишинг, Лтд)


  • Bermeshev T. V. (Siberian Federal University)
  • Podshibyakina E. Yu. (Siberian Federal University)
  • Bundin M. P. (Siberian Federal University)
  • Mazurova E. V. (Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences)
  • Samoilo A. S. (Siberian Federal University)
  • Yasinskii A. S. (Institute for Process Metallurgy and Metal Recycling (IME), RWTH Aachen University)
  • Yushkova O. V. (Siberian Federal University)
  • Voroshilov D. S. (Siberian Federal University)
  • Bespalov V. M. (Siberian Federal University)
  • Zaloga A. N. (Siberian Federal University)
  • Yur'ev P. O. (Siberian Federal University)

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