Тип публикации: статья из журнала
Год издания: 2023
Идентификатор DOI: 10.1134/S1087659622601071
Ключевые слова: hydrothermal synthesis, cenospheres, faujasite, gismondine, zeolite sorbents, radioactive waste
Аннотация: The effect of the hydrothermal synthesis conditions (temperature, duration, mixing), composition, and presynthetic processing of narrow fractions of cenospheres of fly ash, which act as a template and source of Si and Al, on the production of microspherical zeolite materials of the given structural type in the Na2O–H2O–(SiO2–Al2O3)Показать полностьюglass of two molar compositions is studied. The synthesis products are characterized by XRD, SEM-EDS, and low-temperature nitrogen adsorption, and their sorption properties in relation to Cs+ and Sr2+ are studied. The factors contributing to the predominant formation of NaX zeolite of the faujasite structural type are revealed. It is established that zeolite products based on cenospheres with a glass phase content of about 95 wt % demonstrate the highest sorption parameters, including the maximum capacity for Cs+ and Sr2+ of up to 250 and 180 mg/g, distribution coefficient of about 104 and 106 mL/g, and degree of extraction of 99.1 and 99.9%, respectively.
Журнал: Glass Physics and Chemistry
Выпуск журнала: Т.49, №2
Номера страниц: 167-176
ISSN журнала: 10876596
Место издания: Санкт-Петербург
Издатель: Pleiades Publishing, Ltd. (Плеадес Паблишинг, Лтд)