Тип публикации: статья из журнала
Год издания: 2000
Идентификатор DOI: 10.1134/1.626896
Аннотация: The polarized IR absorption spectra of monodomain planar-oriented films of a discotic liquid crystal D-ho are obtained for the first time. The spectral effects induced by the resonance dipole-dipole interaction of molecules, which have been predicted earlier, were observed. It was found that molecular excitations in isotropic and lПоказать полностьюiquid-crystal phases are mixed due to local-filed effects and this mixing affects the relative intensity and dichroism of the absorption bands. New methods were suggested for measuring the local-field parameters in the D-ho phase from intensities and positions of the polarized absorption bands taking into account the mixing of molecular excitations. The two-dimensional crystal lattice of molecular columns was shown to reduce the local-field anisotropy of this phase. (C) 2000 MAIK "Nauka/Interperiodica".
Журнал: OPTICS AND SPECTROSCOPY
Выпуск журнала: Vol. 88, Is. 6
Номера страниц: 891-897
ISSN журнала: 0030400X
Место издания: WASHINGTON
Издатель: OPTICAL SOC AMER