Fluctuations of the Multiplicity of Co3+ Ions and Softening of the Phonon Spectrum of Rare-Earth Cobalt Oxides : научное издание

Описание

Тип публикации: статья из журнала

Год издания: 2022

Идентификатор DOI: 10.1134/s0021364022100575

Аннотация: An unconventional temperature dependence of infrared absorption spectra of rare-earth cobalt oxides LaCoO3 and GdCoO3 has been studied experimentally and theoretically in the temperature range of 3.2–550 K. A quite strong softening of the optical phonon mode has been detected, which cannot be explained by standard lattice anhaПоказать полностьюrmonicity. It has been shown that the redshift of the phonon spectrum is due to the e-lectron–phonon coupling quadratic in the lattice displacement and to fluctuations of the multiplicity of Co3+ ions.

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Издание

Журнал: JETP Letters

Выпуск журнала: Т.115, 10

Номера страниц: 615-619

ISSN журнала: 00213640

Место издания: Москва

Издатель: Pleiades Publishing, Ltd. (Плеадес Паблишинг, Лтд)

Персоны

  • Orlov Yu. S. (Siberian Federal University)
  • Dudnikov V.A. (Kirensky Institute of Physics, Federal Research Center KSC, Siberian Branch, Russian Academy of Sciences)
  • Sokolov A.E. (Siberian Federal University)
  • Ovchinnikova T.M. (Sukachev Institute of Forest, Federal Research Center KSC, Siberian Branch, Russian Academy of Sciences)
  • Shestakov N.P. (Kirensky Institute of Physics, Federal Research Center KSC, Siberian Branch, Russian Academy of Sciences)
  • Ovchinnikov S.G. (Siberian Federal University)

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