Molecular Structure, Electronic Properties, Reactivity (ELF, LOL, and Fukui), and NCI-RDG Studies of the Binary Mixture of Water and Essential Oil of Phlomis bruguieri : научное издание

Описание

Тип публикации: статья из журнала

Год издания: 2023

Идентификатор DOI: 10.3390/molecules28062684

Ключевые слова: caryophyllene oxide, β-Pinene, 1,8-cineol, α-cubebene, β-caryophyllene, essential oil, dft, NCI-RDG, ELF-LOL

Аннотация: Essential oils are volatile oil-like liquids with a characteristic strong smell and taste. They are formed in plants and are then extracted. Essential oils have extremely strong physiological and pharmacological properties, which are used in the medicine, cosmetics, and food industries. In this study, the molecules caryophyllene oxПоказать полностьюide, β-pinene, 1,8-cineol, α-cubebene, and β-caryophyllene, which are the molecules with the highest contents in the essential oil of the plant mentioned in the title, were selected and theoretical calculations describing their interactions with water were performed. Because oil–water mixtures are very important in biology and industry and are ubiquitous in nature, quantum chemical calculations for binary mixtures of water with caryophyllene oxide, β-pinene, 1,8-cineol, α-cubebene, and β-caryophyllene were performed using the density functional theory (DFT)/B3LYP method with a basis of 6–31 G (d, p). Molecular structures, HOMO–LUMO energies, electronic properties, reactivity (ELF, LOL, and Fukui), and NCI-RDG and molecular electrostatic potential (MEP) on surfaces of the main components of Phlomis bruguieri Desf. essential oil were calculated and described.

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Издание

Журнал: Molecules

Выпуск журнала: Т.28, 6

Номера страниц: 2684

ISSN журнала: 14203049

Издатель: MDPI

Персоны

  • Akman Feride (Vocational School of Food, Agriculture and Livestock, University of Bingöl)
  • Demirpolat Azize (Vocational School of Food, Agriculture and Livestock, University of Bingöl)
  • Kazachenko Aleksandr S. (Department of Biological Chemistry with Courses in Medical, Pharmaceutical and Toxicological Chemistry, Krasnoyarsk State Medical University)
  • Kazachenko Anna S. (School of Non-Ferrous Metals and Materials Science, Siberian Federal University)
  • Issaoui Noureddine (Laboratory of Quantum and Statistical Physics, LR18ES18, Faculty of Sciences, University of Monastir)
  • Al-Dossary Omar (Departement of Physics and Astronomy, College of Science, King Saud University)

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