Тип публикации: статья из журнала

Год издания: 2001

Идентификатор DOI: 10.1149/1.1386642

Аннотация: The Seebeck coefficient of a cell with lead electrodes and electrolyte of molten lead chloride and alkali chloride is investigated experimentally and theoretically for mole fractions of PbCl2 between l and 0.3 in alkali chlorides. An equation is derived from irreversible thermodynamics linking the transported entropy of lead ion toПоказать полностьюthe chemical potential of the polarized lead at the surface. The path across the cell is taken to be adiabatic in this derivation. Experimental results indicate that the transported entropy of lead ions depends on the radius of the alkali ion. (C) 2001 The Electrochemical Society.

Журнал: JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Выпуск журнала: Vol. 148, Is. 9

Номера страниц: 364-371

ISSN журнала: 00134651

Место издания: PENNINGTON

Издатель: ELECTROCHEMICAL SOC INC

• Blinov V. (Krasnoyarsk State Acad Nonferrous Met & Gold, Krasnoyarsk 660025, Russia)
• Kjelstrup S. (Graduate School of Energy Science, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan; Norwegian Univ. Sci. Technol., T., 7491 Trondheim, Norway)
• Bedeaux D. (Graduate School of Energy Science, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan; Leiden Institute of Chemistry, Leiden University, Leiden, Netherlands)
• Sharivker V. (Reactive Energy LLC, Sci. Applic. Intl. Corporation, Ottawa, Ont. KIA OH3, Canada)

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