Chemistry of vinylidene complexes-XXVII-new µ-vinylidene MnPt complexes with platinum-coordinated 1-adamantyl isocyanide ligand: spectroscopic, structural and electrochemical study : научное издание


Тип публикации: статья из журнала

Год издания: 2022

Идентификатор DOI: 10.1007/s11243-022-00511-w

Аннотация: New binuclear MnPt µ-vinylidene complexes Cp(CO)2Mn(µ-C=CHPh)Pt(CN–Ad)(L) [L=PPh3 (1a), P(OPri)3 (2a)] bearing a terminal platinum-coordinated 1-adamantyl isocyanide ligand were prepared by the treatment of Cp(CO)2Mn(µ-C=CHPh)Pt(CO)(L) [L=PPh3 (1b), P(OPri)3 (2b)] with CN-Ad. At the same time the reaction between Cp(CO)2Mn(µ-C=CHPhПоказать полностью)Pt(L)2 [L=PPh3 (1c), P(OPri)3 (2c)] and CN-Ad did not proceed. The new complexes were characterized by IR and 1H, 13C, 31P NMR spectroscopy. The molecular structure of Cp(CO)2Mn(µ-C=CHPh)Pt(CN–Ad)[P(OPri)3] (2a) was determined by an X-ray diffraction study. The redox properties of the new complexes and their reactions of chemical oxidation were studied. An influence of the platinum-coordinated 1-adamantyl isocyanide ligand on the properties of the synthesized µ-vinylidene compounds 1a and 2a was revealed.

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Журнал: Transition Metal Chemistry

Номера страниц: 1-11

ISSN журнала: 03404285

Издатель: Springer Science+Business Media B.V., Formerly Kluwer Academic Publishers B.V.


  • Verpekin Victor V. (Institute of Chemistry and Chemical Technology SB RAS)
  • Chudin Oleg S. (Institute of Chemistry and Chemical Technology SB RAS)
  • Kondrasenko Alexander A. (Institute of Chemistry and Chemical Technology SB RAS)
  • Burmakina Galina V. (Institute of Chemistry and Chemical Technology SB RAS)
  • Vasiliev Alexander D. (Siberian Federal University)
  • Zimonin Dmitry V. (Siberian Federal University)
  • Rubaylo Anatoly I. (Siberian Federal University)

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