The role of chemical pressure in the formation of the piezocaloric effect in fluorine–oxygen ferroics

Описание

Тип публикации: статья из журнала

Год издания: 2020

Идентификатор DOI: 10.1080/00150193.2020.1791581

Ключевые слова: 62.50.-p, 64.70.k-, 65.40.g-, caloric effect, entropy, fluorides, high pressure, phase transitions

Аннотация: We performed an analysis of the phase diagrams and piezocaloric properties of fluorine–oxygen ferroics (NH4)2MeOxF6-x (Me: W, Mo, Nb; x: 1, 2) with orthorhombic symmetry. The nature of the influence of chemical pressure on the caloric efficiency has been elucidated. Substitutions of central atoms, Mo → W and Nb → W, lead to an incrПоказать полностьюease in absolute and integral piezocaloric effects. © 2020 Taylor & Francis Group, LLC.

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Издание

Журнал: Ferroelectrics

Выпуск журнала: Vol. 567, Is. 1

Номера страниц: 1-12

ISSN журнала: 00150193

Персоны

  • Flerov Igor (KSC SB RAS, Fed Res Ctr, Kirensky Inst Phys, Krasnoyarsk, Russia; Siberian Fed Univ, Inst Engn Phys & Radioelect, Krasnoyarsk, Russia)
  • Gorev Mikhail (KSC SB RAS, Fed Res Ctr, Kirensky Inst Phys, Krasnoyarsk, Russia; Siberian Fed Univ, Inst Engn Phys & Radioelect, Krasnoyarsk, Russia)