Перевод названия: Composite solid electrolytes with mesoporous oxide additives
Тип публикации: доклад, тезисы доклада, статья из сборника материалов конференций
Конференция: Nanotechnology General Session - 216th ECS Meeting. Сер. "Nanotechnology (General) - 216th ECS Meeting" sponsors: ECS All Divisions. Vienna, 2010
Год издания: 2010
Идентификатор DOI: 10.1149/1.3316110
Аннотация: Nanocomposites RbNO3-A and LiClO4-A (A = MCM-41, SBA-15) were prepared and investigated by electron microscopy, X-ray diffraction, small-angle scattering, thermal analysis and their conductivities were measured. It was shown that in contrast to LiClO4, rubidium nitrate distributes into the oxide matrix non-uniformly. Both RbNO3 andПоказать полностьюLiClO4 transforms to amorphous states, leading to the absence of heat effects associated with melting and other phase transitions and disproportionately strong decrease in intensity of all X-ray diffraction peaks. It was found that the addition of SBA-15 with relatively large pores (7 run) results in much higher increase in the conductivity of RbNO3 than the doping with MCM-41 additive with smaller pores (3.5 nm). ©The Electrochemical Society.
Журнал: ECS TRANSACTIONS
Выпуск журнала: 25
Номера страниц: 35-40
Место издания: Vienna