Crystal structure of catena-(mu(4)-1,3-diethyl-2-thiobarbiturato-O,O',S,S)silver(I)

Описание

Тип публикации: статья из журнала

Год издания: 2015

Идентификатор DOI: 10.1134/S0036023615050071

Ключевые слова: Atoms, Geometry, Hydrogen bonds, Ions, Silver, Sulfur, X ray powder diffraction, Complex 1, Infinite chains, Oxygen atom, Silvers (i), Space Groups, Sulfur atoms, Three-dimensional frameworks, Crystal structure

Аннотация: The crystal structure of catena-(mu(4)-1,3-diethyl-2-thiobarbiturato-O,O',S,S)silver(I) [Ag(mu(4)-DETBA-O,O',S,S] (1), where HDETBA is 1,3-diethyl-2-thiobarbituric acid C8H12N2O2S, has been solved by X-ray powder diffraction. Crystals of complex 1 are monoclinic, a = 7.8339(2) , b = 15.4970(4) , c = 8.7502(2) , beta = 111.916(2)A dПоказать полностьюegrees, V = 985.53(5) (3), space group P2(1)/c, Z = 4. The Ag+ ion is coordinated by two oxygen atoms and two sulfur atoms to form a distorted tetrahedron. Tetrahedra share sulfur atom vertices to form infinite chains linked via bridging DETBA(-) ions into a three-dimensional framework. No hydrogen bonds have been found in the structure, but pi-pi interaction is observed between DETBA(-) ions.

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Издание

Журнал: RUSSIAN JOURNAL OF INORGANIC CHEMISTRY

Выпуск журнала: Vol. 60, Is. 5

Номера страниц: 572-576

ISSN журнала: 00360236

Место издания: NEW YORK

Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER

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