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Synthesis of Prenyl- and Geranyl-Substituted Carbazole Alkaloids by DIBAL-H Promoted Reductive Pyran Ring Opening of Dialkylpyrano[3,2-a]carbazoles : научное издание

Описание

Тип публикации: статья из журнала

Год издания: 2014

Идентификатор DOI: 10.1002/chem.201403645

Аннотация: The DIBAL-H promoted reductive pyran ring opening of dialkylpyrano[3,2-a]carbazoles provides?a direct access to a broad range of prenyl- and geranylsubstituted carbazoles. Formation of a pyran ring followed by reductive ring opening represents a new method for the introduction of prenyl and geranyl groups. In the course of the presПоказать полностьюent work, we achieved the first total syntheses of the following eight carbazole alkaloids: clauraila-E, 7-hydroxyheptaphylline, 7-methoxyheptaphylline, mukoenine-B (clausenatine-A), mukoenine-A (girinimbilol), mahanimbinol (mahanimbilol), euchrestine-A, and isomurrayafoline-B.

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Издание

Журнал: Chemistry - A European Journal

Выпуск журнала: Т. 20, № 31

Номера страниц: 9504-9509

ISSN журнала: 09476539

Издатель: Wiley Interscience

Персоны

  • Hesse R. (Department of Chemistry, Technische Universitt Dresden)
  • Kataeva O. (Department of Chemistry, Technische Universitt Dresden)
  • Schmidt A.W. (Department of Chemistry, Technische Universitt Dresden)
  • Knölker H.-J. (Department of Chemistry, Technische Universitt Dresden)

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