Recovery of noble metals from refractory sulfide black-shale ores


Тип публикации: статья из журнала

Год издания: 2014

Идентификатор DOI: 10.1016/j.hydromet.2014.02.008

Ключевые слова: Black-shale ores, Noble metals, Leaching, Sorption, Selective elution, Atmospheric pressure, Chlorine compounds, Gold deposits, Ion exchange resins, Manganese oxide, Ores, Platinum, Precious metals, Refractory materials, Shale, Silver, Anion exchangers, Carbon adsorbents, Chloride complexes, Initial concentration, Platinum group metals, Refractory sulfides, Thiourea solutions, Gold ore treatment

Аннотация: The processing of refractory sulfide black-shale ores and concentrates from the Sukhoy Log deposit containing gold, silver and platinum group metals (palladium and platinum) was investigated. The noble metals were leached both under atmospheric pressure and at 700 kPa at 200 C in an autoclave. It was found that the preferred leachiПоказать полностьюng method is the chlorination of the ore in HCl/NaCL solutions in the presence of MnO2. The sorption recovery of noble metals on Purolite anion exchangers and carbon adsorbent Calgon GRC-22 was carried out from solution with the following initial concentrations of noble metals (in mg/L): Au-25; Pt-5; Pd-5; and Ag-10 in the presence of 1 M FeCl3, 0.1 M CuCl2, 1 M NaCl and 1 M HCl. It was shown that the chloride complexes of noble metals can be effectively adsorbed from this solution. Then, the selective elution of noble metals from anion exchangers Purolite A170 and Purolite S992 by means of different complex-forming reagents was studied. The best elution results were obtained with Na2SO3 + NaNO2 and thiourea solutions. (C) 2014 Elsevier B.V. All rights reserved.

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Выпуск журнала: Vol. 144

Номера страниц: 156-162

ISSN журнала: 0304386X

Место издания: AMSTERDAM



  • Kononova U.N. (Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Krasnoyarsk 660041, Russia)
  • Patrushev V.V. (Russian Acad Sci, Siberian Dept, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia)
  • Kononov Y.S. (Russian Acad Sci, Siberian Dept, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia)