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The state and catalytic properties of (PD+LN)/SIO2 prepared by grafting of organometallic complexes on the support surface : научное издание

Описание

Тип публикации: статья из журнала

Год издания: 1994

Аннотация: It is found that the activity and selectivity of all bimetallic (Pd + Ln)/SiO2 systems toward methanol in the synthesis from CO and H-2 exceed those of Pd/SiO2. An opposite effect is observed in the propylene hydroformylation process. The assumption is proved that the hydroformylation of olefins occurs on monometallic palladium cluПоказать полностьюsters without participation of the combined Pd-Ln(n+) sites and CO complexes activated on these sites.

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Издание

Журнал: Kinetics and Catalysis

Выпуск журнала: Т. 35, № 1

Номера страниц: 97-101

ISSN журнала: 00231584

Место издания: Москва

Издатель: Pleiades Publishing, Ltd. (Плеадес Паблишинг, Лтд)

Персоны

  • Kovalchuk V.I. (Krasnoyarsk Science Centre of the Siberian Branch of Russian Academy of Science)
  • Nogin Y.K. (Krasnoyarsk Science Centre of the Siberian Branch of Russian Academy of Science)
  • Chesnokov N.V. (Krasnoyarsk Science Centre of the Siberian Branch of Russian Academy of Science)
  • Ryndin Y.A. (Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences)
  • Kuznetsov B.N. (Krasnoyarsk Science Centre of the Siberian Branch of Russian Academy of Science)

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