Тип публикации: статья из журнала
Год издания: 2013
Идентификатор DOI: 10.1134/S0036023613110235
Ключевые слова: Alternating layers, Crystal and molecular structure, Formamidines, Framework structures, Inversion center, Space Groups, Hydrogen bonds, Positive ions, Crystal structure
Аннотация: The crystal and molecular structure of bis(alpha,alpha'-dithio-bis(formamidinium)) bis(mu(2)-chloro)hexachlorodimercurate(II) C4H16Hg2Cl8N8S4 (I), where alpha,alpha'-dithio-bis(formamidine) is C2H6N4S2, was solved. Crystals are monoclinic, a = 8.6417(6) , b = 14.648(1) , c = 10.2111(8) , beta = 104.949(1)A degrees, V = 1248.8(2) (3Показать полностью), space group P2(1)/n, Z = 4. The crystal structure is built of HgCl (4) (2-) ions linked via inversion centers into [Hg2Cl8](4-) pairs and C2H8N4S (2) (2+) cations. [Hg2Cl8](4-) anions and C2H8N4S (2) (2+) cations form alternating layers linked by N-HaEuro broken vertical bar Cl hydrogen bonds into a framework structure.
Журнал: RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Выпуск журнала: Vol. 58, Is. 11
Номера страниц: 1298-1301
ISSN журнала: 00360236
Место издания: NEW YORK
Издатель: MAIK NAUKA/INTERPERIODICA/SPRINGER