Тип публикации: статья из журнала

Год издания: 2011

Идентификатор DOI: 10.1007/s11172-011-0265-x

Ключевые слова: iodophenols, 1-adamantanol, alkylation, trifluoroacetic acid, electrophilic substitution, the Reverden rearrangement

Аннотация: A reaction of 2-iodophenol and 2-iodoanisole with 1-adamantanol in trifluoroacetic acid gives the corresponding 4-(1-adamantyl) derivatives. Similar adamantylation of 4-iodophenol and 4-iodoanisole is accompanied by migration of the iodine atom from para- to ortho-position, giving 4,6-di(1-adamantyl)-2-iodophenol and 4-(1-adamantylПоказать полностью)-2-iodoanisole, respectively, as the reaction products.

Журнал: RUSSIAN CHEMICAL BULLETIN

Выпуск журнала: Vol. 60, Is. 8

Номера страниц: 1776-1777

ISSN журнала: 10665285

Место издания: NEW YORK

Издатель: SPRINGER

• Sokolenko W.A. (Institute of Chemistry and Chemical Technology,Siberian Branch of the Russian Academy of Sciences)
• Svirskaya N.M. (Institute of Chemistry and Chemical Technology,Siberian Branch of the Russian Academy of Sciences)
• Rubailo A.I. (Siberian Federal University)

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