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The New mu-Phenylvinylidene RePt Complexes Containing Platinum-Bound 1-(Isocyanomethylsulfonyl)-4-Methylbenzene : научное издание

Описание

Тип публикации: статья из журнала

Год издания: 2020

Идентификатор DOI: 10.17516/1998-2836-0200

Ключевые слова: rhenium, platinum, vinylidene complexes, heterometallic complexes, carbonyl, isocyanide, electrochemistry

Аннотация: The binuclear mu-vinylidene complexes containing an isocyanide ligand (1-(isocyanomethylsulfonyl)-4-methylbenzene) Cp(CO)(2)RePt(mu-C = CHPh)(TosMIC)(L) [L = PPh3 (1), P(OPri)(3) (2)] were synthesized for the first time. The approach afforded 1 and 2 based on the substitution reactions of a platinum bound carbonyl group in Cp(CO)(2Показать полностью)RePt(mu-C=CHPh)(CO)(L) [L = PPh3 (1a), P(OPri)(3) (2a)] upon addition of 1-(isocyanomethylsulfonyl)-4-methylbenzene. The complexes 1 and 2 were characterized by IR and NMR spectroscopy. Their redox properties were studied.

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Издание

Журнал: JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY

Выпуск журнала: Vol. 13, Is. 4

Номера страниц: 489-498

ISSN журнала: 19982836

Место издания: KRASNOYARSK

Издатель: SIBERIAN FEDERAL UNIV

Персоны

  • Chudin Oleg S.
  • Verpekin Victor V. (FRC Krasnoyarsk Sci Ctr SB RAS, Inst Chem & Chem Technol SB RAS, Krasnoyarsk, RussiaSiberian Fed Univ, Krasnoyarsk, Russia)
  • Kondrasenko Alexander A.
  • Burmakina Galina
  • Zimonin Dmitry
  • Korolkova Irina
  • Rubaylo Anatoly

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