Тип публикации: статья из журнала

Год издания: 2022

Идентификатор DOI: 10.1016/j.solidstatesciences.2022.107027

Ключевые слова: conducting material, dsc, molybdates, potassium, synthesis, thallium

Аннотация: Novel K5-xTlx(Mg0.5Hf1.5)(MoO4)6 (0 ≤ х ≤ 5) oxides were successfully synthesized by solid state reaction. The results indicate the formation of a continuous series of solid solutions with the NASICON-like structure (sp. gr. R3‾c) in the composition range 0 < x < 5. The unit-cell parameters of the solid solutions increase linearly Показать полностьюwith composition, as a consequence of thallium substitution for potassium. The cation conductivity of Tl5Mg0.5Hf1.5(MoO4)6 has been shown to exceed the conductivity of the parent potassium magnesium hafnium molybdate. The highest total conductivity of 2.49 × 10−3 S/cm was found at 831 K for Tl5Mg0.5Hf1.5(MoO4)6. © 2022 Elsevier Masson SAS

Журнал: Solid State Sciences

Выпуск журнала: Vol. 134

Номера страниц: 107027

ISSN журнала: 12932558

Издатель: Elsevier Masson s.r.l.

• Grossman V.G. (Baikal Institute of Nature Management, SB RAS, Sakhyanovoy St., 6, Ulan-Ude, 670047, Russian Federation)
• Molokeev M.S. (Kirensky Institute of Physics, Federal Research Center KSC, Siberian Branch, Academy of Sciences, 50 / 38 Akademgorodok, Krasnoyarsk, 660036, Russian Federation, Siberian Federal University, 82 Svobodniy Av., Krasnoyarsk, 660041, Russian Federation, Department of Physics, Far Eastern State Transport University, Serysheva str. 47, Khabarovsk, 680021, Russian Federation)
• Bazarova J.G. (Baikal Institute of Nature Management, SB RAS, Sakhyanovoy St., 6, Ulan-Ude, 670047, Russian Federation)
• Bazarov B.G. (Baikal Institute of Nature Management, SB RAS, Sakhyanovoy St., 6, Ulan-Ude, 670047, Russian Federation)

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