Тип публикации: статья из журнала
Год издания: 2018
Идентификатор DOI: 10.1016/j.molstruc.2018.03.020
Ключевые слова: Electrochemistry, Heterometallic complexes, Platinum, Rhenium, Vinylidene complexes
Аннотация: The novel heterobinuclear μ-vinylidene complex [Cp(CO)2Re(μ-C=CHPh)Pt(PPh3)(CO)] (1) was isolated from the reaction mixture of [Cp(CO)2Re(μ-C=CHPh)Fe(CO)4] and Pt(PPh3)4 for the first time. Alternative high-yield synthetic approaches to 1 were developed including the reactions of [Cp(CO)2Re(μ-C=CHPh)Pt(PPh3)2] (2) with Co2(CO)8 andПоказать полностьюRh(acac)(CO)2. The complex was characterized by IR and 1H, 13C and 31P NMR spectroscopy, a molecular structure of 1 was determined by X-ray diffraction analysis. The electrochemical behavior of the new complex was studied by cyclic voltammetry at platinum or glassed carbon electrodes and by dc polarography at a dropping mercury electrode. © 2018 Elsevier B.V.
Журнал: Journal of Molecular Structure
Выпуск журнала: Vol. 1163
Номера страниц: 308-315
ISSN журнала: 00222860
Издатель: Elsevier B.V.