Тип публикации: доклад, тезисы доклада, статья из сборника материалов конференций
Конференция: International Multidisciplinary Scientific Geoconference; Albena, BULGARIA; Albena, BULGARIA
Год издания: 2013
Идентификатор DOI: 10.5593/SGEM2013/BA1.V1/S01.007
Ключевые слова: cations, isomorphism, crystal structure, point defects, pyrrhotite, Sations, Basis of calculation, Crystalline structure, Electrical conductivity, Electronic configuration, Isomorphic substitution, Atoms, Exhibitions, Iron ores, Positive ions, Vacancies, Crystal impurities
Аннотация: Based on analysis of the electronic configuration of the impurity in minerals have a crystalline structure such as NiAs (eg, pyrrhotite), a correlation of electrical conductivity, density impurity atoms, and the density cation vacancies. The density cation vacancies increases with the total density of the impurity atoms increases, Показать полностьюthus reducing the conductivity of the crystal decrease. Shown that the nature of these phenomena - decrease in the concentration of electrons in the conduction zone as a result of the capture of an electron vacancy impurity atoms. On the basis of calculations of the density impurity investigated the properties of anionic impurity atoms and analyzed the mechanism of isomorphic substitution of sulfur ions in the structure of pyrrhotite.
Журнал: International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM
Выпуск журнала: Vol. 1
Номера страниц: 47-54
ISSN журнала: 13142704