Silica sequentially modified with polyhexamethylene guanidine and Arsenazo I for preconcentration and ICP-OES determination of metals in natural waters


Тип публикации: статья из журнала

Год издания: 2015

Идентификатор DOI: 10.1016/j.microc.2015.05.022

Ключевые слова: Sorption, Silica, Arsenazo I, Polyhexamethylene guanidine, Preconcentration of metals, River water

Аннотация: Silica based sorbent sequentially modified with polyhexamethylene guanidine and 2-(1,8-dihydroxy-3,6-disulfo-2-naphthylazo)benzenearsonic add (Arsenazo I) was developed and studied in the present work. Conditions for immobilizing Arsenazo I on the aminated silica surface were studied: optimal equilibration time was 10 min, and a maПоказать полностьюximum reagent extraction was achieved between pHs 4 and 7. The stability of the sorbent in highly saline and weakly acidic solutions was examined: it was found that the reagent had not been desorbed from the surface by treatment with dilute solutions of HNO3 and NaCl solutions up to a concentration of 10 g/L. Maximum recovery of Al(III), Ca(II), Cd(II), Co(II), Cu(II), Fe(II), Fe(III), Mg(II), Ni(II), Pb(II), and St(II) was observed in the pH range of 5-7. Metals were desorbed from the surface with 1 M HNO3. Sorptioninductively coupled plasma optical emission method for the determination of metal ions had been developed, including group sorption preconcentration of metal ions from aqueous solutions at pH 7 in the hydrocarbonate buffer medium, their desorption with 1 M HNO3, and inductively coupled plasma optical emission determination. The proposed method was used to determine metal concentration in river waters of Krasnoyarsk Krai. (C) 2015 Elsevier B.V. All rights reserved.

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Выпуск журнала: Vol. 123

Номера страниц: 84-89

ISSN журнала: 0026265X

Место издания: AMSTERDAM



  • Losev Vladimir N. (Siberian Fed Univ, Res & Engn Ctr Kristall, Krasnoyarsk 660041, RussiaTaras Shevchenko Kyiv Natl Univ, Dept Chem, UA-01033 Kiev, Ukraine)
  • Buyko Olga V.
  • Trofimchuk Anatoly K.
  • Zuy Oleg N.