Тип публикации: статья из журнала

Год издания: 2020

Идентификатор DOI: 10.1039/d0dt03530k

Аннотация: A series of reactions of Cp(CO)2MnCCHPh with different gold(i) complexes of [Au-CC-R]n (R = 4-C5H4N, C6H5) and (tht)AuCl yielded one novel trinuclear MnAuMn cluster. The structure of this cluster can be rationalized as being formed of a vinylidene Mn-Au binuclear and Mn-acetylide fragments, and the binding between those is achievedПоказать полностьюmainly through the sharing of the electron pair of the single Mn-C σ-bond of an acetylide unit with the gold center. This journal is © 2020 The Royal Society of Chemistry.

Журнал: Dalton Transactions

Выпуск журнала: Vol. 49, Is. 48

Номера страниц: 17527-17531

• Verpekin Victor V. (Russian Acad Sci, Inst Chem & Chem Technol SB RAS, Krasnoyarsk Res Ctr, Siberian Branch, Akademgorodok 50-24, Krasnoyarsk 660036, Russia)
• Shor Aleksey M. (Russian Acad Sci, Inst Chem & Chem Technol SB RAS, Krasnoyarsk Res Ctr, Siberian Branch, Akademgorodok 50-24, Krasnoyarsk 660036, Russia)
• Vasiliev Alexander D. (Russian Acad Sci, Inst Phys SB RAS, Krasnoyarsk Res Ctr, Siberian Branch, Akademgorodok 50-38, Krasnoyarsk 5038, Russia; Siberian Fed Univ, Svobodny Prospect 79, Krasnoyarsk 660041, Russia)
• Kondrasenko Alexander A. (Russian Acad Sci, Inst Chem & Chem Technol SB RAS, Krasnoyarsk Res Ctr, Siberian Branch, Akademgorodok 50-24, Krasnoyarsk 660036, Russia)
• Chudin Oleg S. (Russian Acad Sci, Inst Chem & Chem Technol SB RAS, Krasnoyarsk Res Ctr, Siberian Branch, Akademgorodok 50-24, Krasnoyarsk 660036, Russia)
• Ivanova-Shor Elena A. (Russian Acad Sci, Inst Chem & Chem Technol SB RAS, Krasnoyarsk Res Ctr, Siberian Branch, Akademgorodok 50-24, Krasnoyarsk 660036, Russia)

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