1. Главная
  2. Публикации
  3. Study of flux crystal growth peculiarities, structure and Raman spectra of double (Mn,Ni)3BO5and triple (Mn,Ni,Cu)3BO5oxyborates with ludwigite structure

Study of flux crystal growth peculiarities, structure and Raman spectra of double (Mn,Ni)3BO5and triple (Mn,Ni,Cu)3BO5oxyborates with ludwigite structure

Описание

Тип публикации: статья из журнала

Год издания: 2021

Идентификатор DOI: 10.1039/d1ce00750e

Аннотация: Crystallization of heterovalent double (Mn,Ni)3BO5 and triple (Mn,Ni,Cu)3BO5 oxyborates with the ludwigite structure is studied in fluxes based on Bi2Mo3O12 diluted with Na2CO3 or Li2CO3 carbonates. Single crystals of five (Mn,Ni)3BO5 and three (Mn,Ni,Cu)3BO5 compounds with different cation ratios are obtained. The ion concentratioПоказать полностьюn is determined from the analysis of the lattice parameters by powder and single crystal XRD. The comparative analysis of the polarized Raman spectra of double and triple ludwigites is presented. The actual high nickel and small copper concentrations in the crystals are discussed. The hierarchy of chemical bonds in the fluxes used in addition to the approach involving stabilization of the manganese valence state using solvent components is estimated. © 2021 The Royal Society of Chemistry.

Ссылки на полный текст

Издание

Журнал: CrystEngComm

Выпуск журнала: Vol. 23, Is. 33

Номера страниц: 5624-5635

ISSN журнала: 14668033

Издатель: Royal Society of Chemistry

Персоны

  • Moshkina E. (Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation)
  • Bovina A. (Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation)
  • Molokeev M. (Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation, Research and Development Department, Kemerovo State University, Kemerovo, 650000, Russian Federation)
  • Krylov A. (Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation)
  • Shabanov A. (Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation, Federal Research Center, Krasnoyarsk Science Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation)
  • Chernyshov A. (Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation, Reshetnev Siberian State University of Science and Technology, Krasnoyarsk, 660037, Russian Federation)
  • Sofronova S. (Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation)

Вхождение в базы данных