Molecular structure of a new tetranuclear mu(2):mu(3)-bis-vinylidene cluster, Cp-2(CO)(4)RePd(mu-C=CHPh)RePd(mu(3)-C=CHPh)(eta(2)-dppe)

Описание

Тип публикации: статья из журнала

Год издания: 2015

Идентификатор DOI: 10.1016/j.poly.2015.01.028

Ключевые слова: Rhenium, Palladium, Vinylidene complexes, Heterometallic complexes, X-ray diffraction

Аннотация: The novel tetranuclear di-vinylidene complex Cp-2(CO)(4)RePd(mu(2)-C=CHPh)RePd(mu(3)-C=CHPh)(dppe) was isolated and characterized by X-ray diffraction. This cluster consists of two RePd fragments linked to each other through the bonding of the palladium atom in the [Cp(CO)(2)RePd(mu-C=CHPh)] fragment to the carbonyl and vinylidene Показать полностьюligands in the Cp(CO)(2)RePd(mu-C=CHPh)(dppe) fragment. (C) 2015 Elsevier Ltd. All rights reserved.

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Издание

Журнал: POLYHEDRON

Выпуск журнала: Vol. 90

Номера страниц: 104-107

ISSN журнала: 02775387

Место издания: OXFORD

Издатель: PERGAMON-ELSEVIER SCIENCE LTD

Персоны

  • Verpekin V.V. (Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences)
  • Chudin O.S. (Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences)
  • Kondrasenko A.A. (Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences)
  • Pavlenko N.I. (Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences)
  • Rubaylo A.I. (Siberian Federal University)
  • Vasiliev A.D. (Siberian Federal University)
  • Kreindlin A.Z. (A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences)